So far only one use case, because (a) I haven't had time to write about the other ones, and (b) this was the one that came to mind quite strongly today.
There has been talk about this junction now and then; both on the #perl6 channel and in S09. Its semantics is pretty clear: put a list in a position where a scalar is expected, causing the statement to be executed for each of the list's elements.
%hash{each <foo bar baz>} = True; # assign each hash key
promote(each @employees); # call with each element as argument