Please refer to ZFS 2-3x slower than EXT4 to see how ZFS defaults + Postgres defaults severely underperform EXT4 defaults + Postgres defaults (and also to know more about the system on which these benchmarks were performed). This page documents how to tune ZFS + Postgres to give better performance for the tpcb-like benchmark.
Please do not copy these settings blindly because I am myself not clear on why/how these settings had the impact they did. For example, I cannot explain why full_page_writes=off independently did not give that much boost, nor did an optimized PG configuration. However, putting both of them together gave a 2-4x boost compared to baseline numbers.