Code to add Album menu as Top Level WordPress Profile Menu.

function.php

<?php 
/**
 * Function to add Album menu as main menu in WordPress Profile menu.
 */
if ( ! function_exists( 'rtmedia_add_album_main_menu' ) ) {
	function rtmedia_add_album_main_menu() {
		// Please change the page_slug if you want from here
		$page_slug = 'album';
		$page_title = __('Album','buddypress-media' );
		// check if RTMEDIA_MEDIA_SLUG is already defined
		if ( defined( 'RTMEDIA_MEDIA_SLUG' ) ) {
			global $wp_admin_bar;
			$wp_admin_bar->add_menu( array(
				'parent' => 'my-account',
				'id'     => 'my-account-media-' . $page_slug,
				'title'  => $page_title,
				'href'   => trailingslashit( get_rtmedia_user_link( get_current_user_id() ) ) . RTMEDIA_MEDIA_SLUG .'/'.$page_slug,
				'meta' => array('class'=>'menupop')
			) );
		}
	}
}
add_action( 'rtmedia_add_admin_bar_media_sub_menu', 'rtmedia_add_album_main_menu', 10 );