Copy all files of a VLC .xspf to a folder with the same name. Place the xspf files alongside the script.

playlist.py

# -*- coding: utf-8 -*-
import os
from urllib.parse import unquote
from xml.dom import minidom
import shutil
import sys

# Read all files alongside this script
for FILE in os.listdir('.'):
    if '.xspf' in FILE:
        DEST_DIR = FILE.replace('.xspf', '')

        # Parse xml and get the file list
        file_array = []
        xmldoc = minidom.parse(FILE)
        itemlist = xmldoc.getElementsByTagName('location')
        for s in itemlist:
            filevalue = s.firstChild.nodeValue
            filevalue = filevalue.replace('file:///', '')
            filevalue = unquote(filevalue)
            file_array.append(filevalue)

        # Creating folder
        if not os.path.exists(DEST_DIR):
            os.makedirs(DEST_DIR)

        # Copy files to new folder
        for file in file_array:
            head, tail = os.path.split(file)
            if os.path.isfile(file):
                shutil.copy(file, './' + DEST_DIR + '/' + tail)