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Created March 23, 2016 19:40
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DBCSR| Multiplication driver BLAS
DBCSR| Multrec recursion limit 512
DBCSR| Multiplication stack size 1000
DBCSR| Maximum elements for images UNLIMITED
DBCSR| Randmat seed 12341313
DBCSR| Multiplication size stacks 3
DBCSR| Use MPI memory allocation T
DBCSR| Use RMA algorithm F
DBCSR| Use Communication thread T
DBCSR| Communication thread load 87
**** **** ****** ** PROGRAM STARTED AT 2016-03-23 14:32:58.578
***** ** *** *** ** PROGRAM STARTED ON aci-278.chtc.wisc.edu
** **** ****** PROGRAM STARTED BY ehermes
***** ** ** ** ** PROGRAM PROCESS ID 3698683
**** ** ******* ** PROGRAM STARTED IN /home/ehermes/test/cp2k/tddft
CP2K| version string: CP2K version 3.0
CP2K| source code revision number: svn:16458
CP2K| cp2kflags: libint fftw3 libxc pexsi elpa3 parallel mpi2 scalapack libgrid
CP2K| max_contr=4
CP2K| is freely available from https://www.cp2k.org/
CP2K| Program compiled at Thu Mar 17 20:15:53 CDT 2016
CP2K| Program compiled on aci-service-2.chtc.wisc.edu
CP2K| Program compiled for Linux-x86-64-gfortran
CP2K| Data directory path /home/ehermes/local/apps/cp2k/data
CP2K| Input file name qtz_tddft.inp
GLOBAL| Force Environment number 1
GLOBAL| Basis set file name POTENTIAL
GLOBAL| MM Potential file name MM_POTENTIAL
GLOBAL| Coordinate file name __STD_INPUT__
GLOBAL| Method name CP2K
GLOBAL| Project name qtz_tddft
GLOBAL| Preferred FFT library FFTW3
GLOBAL| Preferred diagonalization lib. SL
GLOBAL| Run type SPECTRA
GLOBAL| All-to-all communication in single precision F
GLOBAL| FFTs using library dependent lengths F
GLOBAL| Global print level MEDIUM
GLOBAL| Total number of message passing processes 20
GLOBAL| Number of threads for this process 1
GLOBAL| This output is from process 0
GLOBAL| CPU model name : Intel(R) Xeon(R) CPU E5-2670 v2 @ 2.50GHz
MEMORY| system memory details [Kb]
MEMORY| rank 0 min max average
MEMORY| MemTotal 132097332 132097332 132097332 132097332
MEMORY| MemFree 118760284 118760284 118760284 118760284
MEMORY| Buffers 207872 207872 207872 207872
MEMORY| Cached 6194116 6194116 6194116 6194116
MEMORY| Slab 2066636 2066636 2066636 2066636
MEMORY| SReclaimable 1475268 1475268 1475268 1475268
MEMORY| MemLikelyFree 126637540 126637540 126637540 126637540
*** Fundamental physical constants (SI units) ***
*** Literature: B. J. Mohr and B. N. Taylor,
*** CODATA recommended values of the fundamental physical
*** constants: 2006, Web Version 5.1
*** http://physics.nist.gov/constants
Speed of light in vacuum [m/s] 2.99792458000000E+08
Magnetic constant or permeability of vacuum [N/A**2] 1.25663706143592E-06
Electric constant or permittivity of vacuum [F/m] 8.85418781762039E-12
Planck constant (h) [J*s] 6.62606896000000E-34
Planck constant (h-bar) [J*s] 1.05457162825177E-34
Elementary charge [C] 1.60217648700000E-19
Electron mass [kg] 9.10938215000000E-31
Electron g factor [ ] -2.00231930436220E+00
Proton mass [kg] 1.67262163700000E-27
Fine-structure constant 7.29735253760000E-03
Rydberg constant [1/m] 1.09737315685270E+07
Avogadro constant [1/mol] 6.02214179000000E+23
Boltzmann constant [J/K] 1.38065040000000E-23
Atomic mass unit [kg] 1.66053878200000E-27
Bohr radius [m] 5.29177208590000E-11
*** Conversion factors ***
[u] -> [a.u.] 1.82288848426455E+03
[Angstrom] -> [Bohr] = [a.u.] 1.88972613288564E+00
[a.u.] = [Bohr] -> [Angstrom] 5.29177208590000E-01
[a.u.] -> [s] 2.41888432650478E-17
[a.u.] -> [fs] 2.41888432650478E-02
[a.u.] -> [J] 4.35974393937059E-18
[a.u.] -> [N] 8.23872205491840E-08
[a.u.] -> [K] 3.15774647902944E+05
[a.u.] -> [kJ/mol] 2.62549961709828E+03
[a.u.] -> [kcal/mol] 6.27509468713739E+02
[a.u.] -> [Pa] 2.94210107994716E+13
[a.u.] -> [bar] 2.94210107994716E+08
[a.u.] -> [atm] 2.90362800883016E+08
[a.u.] -> [eV] 2.72113838565563E+01
[a.u.] -> [Hz] 6.57968392072181E+15
[a.u.] -> [1/cm] (wave numbers) 2.19474631370540E+05
[a.u./Bohr**2] -> [1/cm] 5.14048714338585E+03
CELL_TOP| Volume [angstrom^3]: 817.649
CELL_TOP| Vector a [angstrom 8.592 0.000 0.001 |a| = 8.592
CELL_TOP| Vector b [angstrom -4.296 7.441 -0.000 |b| = 8.592
CELL_TOP| Vector c [angstrom 0.001 -0.000 12.789 |c| = 12.789
CELL_TOP| Angle (b,c), alpha [degree]: 90.006
CELL_TOP| Angle (a,c), beta [degree]: 89.993
CELL_TOP| Angle (a,b), gamma [degree]: 119.999
CELL_TOP| Numerically orthorhombic: NO
GENERATE| Preliminary Number of Bonds generated: 0
GENERATE| Achieved consistency in connectivity generation.
CELL| Volume [angstrom^3]: 817.649
CELL| Vector a [angstrom]: 8.592 0.000 0.001 |a| = 8.592
CELL| Vector b [angstrom]: -4.296 7.441 -0.000 |b| = 8.592
CELL| Vector c [angstrom]: 0.001 -0.000 12.789 |c| = 12.789
CELL| Angle (b,c), alpha [degree]: 90.006
CELL| Angle (a,c), beta [degree]: 89.993
CELL| Angle (a,b), gamma [degree]: 119.999
CELL| Numerically orthorhombic: NO
CELL_REF| Volume [angstrom^3]: 817.649
CELL_REF| Vector a [angstrom 8.592 0.000 0.001 |a| = 8.592
CELL_REF| Vector b [angstrom -4.296 7.441 -0.000 |b| = 8.592
CELL_REF| Vector c [angstrom 0.001 -0.000 12.789 |c| = 12.789
CELL_REF| Angle (b,c), alpha [degree]: 90.006
CELL_REF| Angle (a,c), beta [degree]: 89.993
CELL_REF| Angle (a,b), gamma [degree]: 119.999
CELL_REF| Numerically orthorhombic: NO
*******************************************************************************
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** ####### ##### ## ##### ## ## #### ## ##### ## **
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** **
** ... make the atoms dance **
** **
** Copyright (C) by CP2K Developers Group (2000 - 2015) **
** **
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DFT| Spin restricted Kohn-Sham (RKS) calculation RKS
DFT| Multiplicity 1
DFT| Number of spin states 1
DFT| Charge 0
DFT| Self-interaction correction (SIC) NO
DFT| Cutoffs: density 1.000000E-10
DFT| gradient 1.000000E-10
DFT| tau 1.000000E-10
DFT| cutoff_smoothing_range 0.000000E+00
DFT| XC density smoothing NONE
DFT| XC derivatives PW
FUNCTIONAL| ROUTINE=NEW
FUNCTIONAL| PBE:
FUNCTIONAL| J.P.Perdew, K.Burke, M.Ernzerhof, Phys. Rev. Letter, vol. 77, n 18,
FUNCTIONAL| pp. 3865-3868, (1996){spin unpolarized}
QS| Method: GAPW
QS| Density plane wave grid type NON-SPHERICAL FULLSPACE
QS| Number of grid levels: 4
QS| Density cutoff [a.u.]: 250.0
QS| Multi grid cutoff [a.u.]: 1) grid level 250.0
QS| 2) grid level 83.3
QS| 3) grid level 27.8
QS| 4) grid level 9.3
QS| Grid level progression factor: 3.0
QS| Relative density cutoff [a.u.]: 40.0
QS| Consistent realspace mapping and integration
QS| Interaction thresholds: eps_pgf_orb: 1.0E-05
QS| eps_filter_matrix: 0.0E+00
QS| eps_core_charge: 1.0E-12
QS| eps_rho_gspace: 1.0E-10
QS| eps_rho_rspace: 1.0E-10
QS| eps_gvg_rspace: 1.0E-05
QS| eps_ppl: 1.0E-02
QS| eps_ppnl: 1.0E-07
QS| GAPW| eps_fit: 1.0E-04
QS| GAPW| eps_iso: 1.0E-12
QS| GAPW| eps_svd: 1.0E-08
QS| GAPW| eps_cpc: 1.0E-10
QS| GAPW| atom-r-grid: quadrature: GC_LOG
QS| GAPW| atom-s-grid: max l : 4
QS| GAPW| max_l_rho0 : 2
ATOMIC KIND INFORMATION
1. Atomic kind: H Number of atoms: 30
Orbital Basis Set DZVP-ALL
Number of orbital shell sets: 3
Number of orbital shells: 3
Number of primitive Cartesian functions: 6
Number of Cartesian basis functions: 5
Number of spherical basis functions: 5
Norm type: 2
Normalised Cartesian orbitals:
Set Shell Orbital Exponent Coefficient
1 1 1s 50.999180 0.131396
7.483218 0.237746
1.777468 0.324597
0.519329 0.312139
2 1 2s 0.154110 0.175301
3 1 2px 0.700000 0.912668
3 1 2py 0.700000 0.912668
3 1 2pz 0.700000 0.912668
The atoms of this atomic kind are PAW atoms (GAPW):
Hard Gaussian function radius: 1.200
Rho0 radius: 1.200
Maximum GTO radius used for PAW projector construction: 24.566
GAPW Soft Basis Set DZVP-ALL_soft
Number of orbital shell sets: 3
Number of orbital shells: 3
Number of primitive Cartesian functions: 4
Number of Cartesian basis functions: 5
Number of spherical basis functions: 5
Norm type: 2
Normalised Cartesian orbitals:
Set Shell Orbital Exponent Coefficient
1 1 1s 1.777468 0.324597
0.519329 0.312139
2 1 2s 0.154110 0.175301
3 1 2px 0.700000 0.912668
3 1 2py 0.700000 0.912668
3 1 2pz 0.700000 0.912668
Potential information for ALL
Description: All-electron potential
Krack, Parrinello, PCCP 2, 2105 (2000)
Gaussian exponent of the core charge distribution: 12.500000
Electronic configuration (s p d ...): 1 0 0
2. Atomic kind: C Number of atoms: 24
Orbital Basis Set DZVP-ALL
Number of orbital shell sets: 6
Number of orbital shells: 6
Number of primitive Cartesian functions: 15
Number of Cartesian basis functions: 15
Number of spherical basis functions: 14
Norm type: 2
Normalised Cartesian orbitals:
Set Shell Orbital Exponent Coefficient
1 1 1s 2808.064000 0.554753
421.138300 1.022550
95.586620 1.646735
26.739000 2.076920
8.432827 1.690687
2.760582 0.509556
2 1 2s 5.447004 -0.364740
0.479242 0.430678
3 1 3s 0.146156 0.168470
4 1 2px 18.130850 1.083577
4.099883 1.019709
1.185837 0.689261
0.368597 0.258915
4 1 2py 18.130850 1.083577
4.099883 1.019709
1.185837 0.689261
0.368597 0.258915
4 1 2pz 18.130850 1.083577
4.099883 1.019709
1.185837 0.689261
0.368597 0.258915
5 1 3px 0.109720 0.090011
5 1 3py 0.109720 0.090011
5 1 3pz 0.109720 0.090011
6 1 3dx2 0.600000 0.673247
6 1 3dxy 0.600000 1.166097
6 1 3dxz 0.600000 1.166097
6 1 3dy2 0.600000 0.673247
6 1 3dyz 0.600000 1.166097
6 1 3dz2 0.600000 0.673247
The atoms of this atomic kind are PAW atoms (GAPW):
Hard Gaussian function radius: 1.512
Rho0 radius: 1.512
Maximum GTO radius used for PAW projector construction: 24.566
GAPW Soft Basis Set DZVP-ALL_soft
Number of orbital shell sets: 6
Number of orbital shells: 6
Number of primitive Cartesian functions: 8
Number of Cartesian basis functions: 15
Number of spherical basis functions: 14
Norm type: 2
Normalised Cartesian orbitals:
Set Shell Orbital Exponent Coefficient
1 1 1s 2.760582 0.509556
2 1 2s 0.479242 0.430678
3 1 3s 0.146156 0.168470
4 1 2px 4.099883 1.019709
1.185837 0.689261
0.368597 0.258915
4 1 2py 4.099883 1.019709
1.185837 0.689261
0.368597 0.258915
4 1 2pz 4.099883 1.019709
1.185837 0.689261
0.368597 0.258915
5 1 3px 0.109720 0.090011
5 1 3py 0.109720 0.090011
5 1 3pz 0.109720 0.090011
6 1 3dx2 0.600000 0.673247
6 1 3dxy 0.600000 1.166097
6 1 3dxz 0.600000 1.166097
6 1 3dy2 0.600000 0.673247
6 1 3dyz 0.600000 1.166097
6 1 3dz2 0.600000 0.673247
Potential information for ALL
Description: All-electron potential
Krack, Parrinello, PCCP 2, 2105 (2000)
Gaussian exponent of the core charge distribution: 4.109048
Electronic configuration (s p d ...): 4 2 0
3. Atomic kind: N Number of atoms: 12
Orbital Basis Set DZVP-ALL
Number of orbital shell sets: 6
Number of orbital shells: 6
Number of primitive Cartesian functions: 15
Number of Cartesian basis functions: 15
Number of spherical basis functions: 14
Norm type: 2
Normalised Cartesian orbitals:
Set Shell Orbital Exponent Coefficient
1 1 1s 3845.415000 0.702538
577.533200 1.293696
131.319800 2.083840
36.823780 2.644414
11.670120 2.159244
3.854260 0.650495
2 1 2s 7.829561 -0.480745
0.687735 0.564733
3 1 3s 0.204039 0.216369
4 1 2px 26.809840 1.721404
6.068154 1.675733
1.767626 1.146637
0.546673 0.421221
4 1 2py 26.809840 1.721404
6.068154 1.675733
1.767626 1.146637
0.546673 0.421221
4 1 2pz 26.809840 1.721404
6.068154 1.675733
1.767626 1.146637
0.546673 0.421221
5 1 3px 0.158729 0.142810
5 1 3py 0.158729 0.142810
5 1 3pz 0.158729 0.142810
6 1 3dx2 0.700000 0.881721
6 1 3dxy 0.700000 1.527185
6 1 3dxz 0.700000 1.527185
6 1 3dy2 0.700000 0.881721
6 1 3dyz 0.700000 1.527185
6 1 3dz2 0.700000 0.881721
The atoms of this atomic kind are PAW atoms (GAPW):
Hard Gaussian function radius: 1.512
Rho0 radius: 1.512
Maximum GTO radius used for PAW projector construction: 24.566
GAPW Soft Basis Set DZVP-ALL_soft
Number of orbital shell sets: 6
Number of orbital shells: 6
Number of primitive Cartesian functions: 7
Number of Cartesian basis functions: 15
Number of spherical basis functions: 14
Norm type: 2
Normalised Cartesian orbitals:
Set Shell Orbital Exponent Coefficient
1 1 1s 3.854260 0.650495
2 1 2s 0.687735 0.564733
3 1 3s 0.204039 0.216369
4 1 2px 1.767626 1.146637
0.546673 0.421221
4 1 2py 1.767626 1.146637
0.546673 0.421221
4 1 2pz 1.767626 1.146637
0.546673 0.421221
5 1 3px 0.158729 0.142810
5 1 3py 0.158729 0.142810
5 1 3pz 0.158729 0.142810
6 1 3dx2 0.700000 0.881721
6 1 3dxy 0.700000 1.527185
6 1 3dxz 0.700000 1.527185
6 1 3dy2 0.700000 0.881721
6 1 3dyz 0.700000 1.527185
6 1 3dz2 0.700000 0.881721
Potential information for ALL
Description: All-electron potential
Krack, Parrinello, PCCP 2, 2105 (2000)
Gaussian exponent of the core charge distribution: 5.979100
Electronic configuration (s p d ...): 4 3 0
4. Atomic kind: Zn Number of atoms: 3
Orbital Basis Set DZVP-ALL
Number of orbital shell sets: 10
Number of orbital shells: 10
Number of primitive Cartesian functions: 29
Number of Cartesian basis functions: 26
Number of spherical basis functions: 24
Norm type: 2
Normalised Cartesian orbitals:
Set Shell Orbital Exponent Coefficient
1 1 1s 82904.220000 -6.028644
12444.230000 -11.111913
2829.853000 -18.220192
797.892900 -24.202422
259.064700 -21.556338
89.079510 -7.582451
2 1 2s 173.681700 -3.653996
20.166500 4.249158
8.247082 1.553243
3 1 3s 15.316580 -1.220788
2.455749 0.991543
0.954878 0.290810
4 1 4s 1.410003 -0.236881
0.169344 0.206870
5 1 5s 0.059221 0.085559
6 1 2px 1085.178000 78.357670
256.180900 97.070893
81.140250 89.358436
29.222520 49.115632
10.793700 9.521641
6 1 2py 1085.178000 78.357670
256.180900 97.070893
81.140250 89.358436
29.222520 49.115632
10.793700 9.521641
6 1 2pz 1085.178000 78.357670
256.180900 97.070893
81.140250 89.358436
29.222520 49.115632
10.793700 9.521641
7 1 3px 5.841290 4.287290
2.226366 2.118007
0.821164 0.275010
7 1 3py 5.841290 4.287290
2.226366 2.118007
0.821164 0.275010
7 1 3pz 5.841290 4.287290
2.226366 2.118007
0.821164 0.275010
8 1 4px 0.169000 0.154454
8 1 4py 0.169000 0.154454
8 1 4pz 0.169000 0.154454
9 1 3dx2 38.093470 -58.352917
10.423760 -27.475142
3.253252 -6.462861
0.909753 -0.654167
9 1 3dxy 38.093470 -101.070218
10.423760 -47.588342
3.253252 -11.194003
0.909753 -1.133051
9 1 3dxz 38.093470 -101.070218
10.423760 -47.588342
3.253252 -11.194003
0.909753 -1.133051
9 1 3dy2 38.093470 -58.352917
10.423760 -27.475142
3.253252 -6.462861
0.909753 -0.654167
9 1 3dyz 38.093470 -101.070218
10.423760 -47.588342
3.253252 -11.194003
0.909753 -1.133051
9 1 3dz2 38.093470 -58.352917
10.423760 -27.475142
3.253252 -6.462861
0.909753 -0.654167
10 1 4dx2 0.172000 0.075611
10 1 4dxy 0.172000 0.130962
10 1 4dxz 0.172000 0.130962
10 1 4dy2 0.172000 0.075611
10 1 4dyz 0.172000 0.130962
10 1 4dz2 0.172000 0.075611
The atoms of this atomic kind are PAW atoms (GAPW):
Hard Gaussian function radius: 1.512
Rho0 radius: 1.512
Maximum GTO radius used for PAW projector construction: 24.566
GAPW Soft Basis Set DZVP-ALL_soft
Number of orbital shell sets: 10
Number of orbital shells: 10
Number of primitive Cartesian functions: 11
Number of Cartesian basis functions: 26
Number of spherical basis functions: 24
Norm type: 2
Normalised Cartesian orbitals:
Set Shell Orbital Exponent Coefficient
1 1 1s
2 1 2s
3 1 3s 2.455749 0.991543
0.954878 0.290810
4 1 4s 1.410003 -0.236881
0.169344 0.206870
5 1 5s 0.059221 0.085559
6 1 2px
6 1 2py
6 1 2pz
7 1 3px 2.226366 2.118007
0.821164 0.275010
7 1 3py 2.226366 2.118007
0.821164 0.275010
7 1 3pz 2.226366 2.118007
0.821164 0.275010
8 1 4px 0.169000 0.154454
8 1 4py 0.169000 0.154454
8 1 4pz 0.169000 0.154454
9 1 3dx2 3.253252 -6.462861
0.909753 -0.654167
9 1 3dxy 3.253252 -11.194003
0.909753 -1.133051
9 1 3dxz 3.253252 -11.194003
0.909753 -1.133051
9 1 3dy2 3.253252 -6.462861
0.909753 -0.654167
9 1 3dyz 3.253252 -11.194003
0.909753 -1.133051
9 1 3dz2 3.253252 -6.462861
0.909753 -0.654167
10 1 4dx2 0.172000 0.075611
10 1 4dxy 0.172000 0.130962
10 1 4dxz 0.172000 0.130962
10 1 4dy2 0.172000 0.075611
10 1 4dyz 0.172000 0.130962
10 1 4dz2 0.172000 0.075611
Potential information for ALL
Description: All-electron potential
Krack, Parrinello, PCCP 2, 2105 (2000)
Gaussian exponent of the core charge distribution: 4.325260
Electronic configuration (s p d ...): 8 12 10
MOLECULE KIND INFORMATION
All atoms are their own molecule, skipping detailed information
TOTAL NUMBERS AND MAXIMUM NUMBERS
Total number of - Atomic kinds: 4
- Atoms: 69
- Shell sets: 336
- Shells: 336
- Primitive Cartesian functions: 807
- Cartesian basis functions: 768
- Spherical basis functions: 726
Maximum angular momentum of the orbital basis functions: 2
MODULE QUICKSTEP: ATOMIC COORDINATES IN angstrom
Atom Kind Element X Y Z Z(eff) Mass
1 1 H 1 4.989282 2.957227 7.565434 1.00 1.0079
2 1 H 1 3.495851 2.802481 11.800874 1.00 1.0079
3 1 H 1 4.360334 1.592013 3.332559 1.00 1.0079
4 1 H 1 0.680255 4.428340 0.987604 1.00 1.0079
5 1 H 1 -0.800213 4.571142 9.456316 1.00 1.0079
6 1 H 1 5.386582 2.267734 9.164359 1.00 1.0079
7 1 H 1 3.926006 3.569434 0.565930 1.00 1.0079
8 1 H 1 3.616318 1.601673 4.954886 1.00 1.0079
9 1 H 1 1.128626 5.184022 12.222060 1.00 1.0079
10 1 H 1 -0.419863 3.932020 7.833813 1.00 1.0079
11 1 H 1 4.410668 3.749412 9.043072 1.00 1.0079
12 1 H 1 3.129758 1.979798 0.540380 1.00 1.0079
13 1 H 1 5.381836 1.715725 4.777031 1.00 1.0079
14 1 H 1 0.150293 3.699417 12.248685 1.00 1.0079
15 1 H 1 -1.204363 5.517747 8.012128 1.00 1.0079
16 1 H 1 -0.390690 1.397494 1.025207 1.00 1.0079
17 1 H 1 3.264075 6.383520 5.301408 1.00 1.0079
18 1 H 1 -2.919764 7.078127 9.578622 1.00 1.0079
19 1 H 1 3.897022 6.018409 7.487292 1.00 1.0079
20 1 H 1 7.590809 1.010129 3.209759 1.00 1.0079
21 1 H 1 0.770995 0.955170 5.331021 1.00 1.0079
22 1 H 1 7.357313 0.151566 9.599397 1.00 1.0079
23 1 H 1 4.758955 6.291929 1.089210 1.00 1.0079
24 1 H 1 -3.547280 6.446815 3.189277 1.00 1.0079
25 1 H 1 3.070172 7.266650 11.699463 1.00 1.0079
26 1 H 1 0.442459 1.145082 7.457516 1.00 1.0079
27 1 H 1 1.406598 0.360288 11.763233 1.00 1.0079
28 1 H 1 1.041692 5.693998 3.744975 1.00 1.0079
29 1 H 1 -0.729407 5.798071 3.624576 1.00 1.0079
30 1 H 1 0.067058 5.799016 5.223095 1.00 1.0079
31 2 C 6 3.367045 1.942308 8.539473 6.00 12.0107
32 2 C 6 5.206908 1.954558 12.779758 6.00 12.0107
33 2 C 6 4.309660 3.512772 4.291991 6.00 12.0107
34 2 C 6 -0.910132 5.485763 0.008859 6.00 12.0107
35 2 C 6 0.888092 5.488337 8.496822 6.00 12.0107
36 2 C 6 7.250029 1.376548 0.505699 6.00 12.0107
37 2 C 6 3.766694 5.570911 4.787690 6.00 12.0107
38 2 C 6 1.838460 0.467628 9.055983 6.00 12.0107
39 2 C 6 2.941910 6.047361 8.000953 6.00 12.0107
40 2 C 6 -0.513631 1.825452 3.732491 6.00 12.0107
41 2 C 6 0.349398 1.800440 4.798896 6.00 12.0107
42 2 C 6 2.532585 6.812377 9.063243 6.00 12.0107
43 2 C 6 -2.890047 6.230962 0.558063 6.00 12.0107
44 2 C 6 4.633923 5.598936 3.725398 6.00 12.0107
45 2 C 6 6.842048 0.612379 12.230536 6.00 12.0107
46 2 C 6 4.607388 2.770898 8.579304 6.00 12.0107
47 2 C 6 3.868669 2.614988 0.028744 6.00 12.0107
48 2 C 6 4.420158 2.025547 4.340910 6.00 12.0107
49 2 C 6 0.331048 4.657168 12.759850 6.00 12.0107
50 2 C 6 -0.454929 4.839986 8.447932 6.00 12.0107
51 2 C 6 0.096232 5.374997 4.209312 6.00 12.0107
52 2 C 6 1.385344 1.202653 7.989612 6.00 12.0107
53 2 C 6 -2.432035 6.966508 12.282892 6.00 12.0107
54 2 C 6 -0.001035 3.886559 4.249233 6.00 12.0107
55 3 N 7 6.210499 2.220362 0.855511 7.00 14.0067
56 3 N 7 3.568092 4.249875 5.148118 7.00 14.0067
57 3 N 7 3.090607 0.942506 9.405609 7.00 14.0067
58 3 N 7 1.897157 5.214805 7.640574 7.00 14.0067
59 3 N 7 -0.728507 3.147290 3.383070 7.00 14.0067
60 3 N 7 0.664774 3.106063 5.130360 7.00 14.0067
61 3 N 7 1.235866 6.450011 9.382284 7.00 14.0067
62 3 N 7 -1.921101 5.299952 0.888375 7.00 14.0067
63 3 N 7 4.968563 4.294764 3.406463 7.00 14.0067
64 3 N 7 5.551358 0.986154 11.900287 7.00 14.0067
65 3 N 7 2.358336 2.128600 7.658376 7.00 14.0067
66 3 N 7 -1.181553 6.488017 11.933169 7.00 14.0067
67 4 Zn 30 2.113493 3.660039 6.394298 30.00 65.3800
68 4 Zn 30 6.415765 3.751284 2.134389 30.00 65.3800
69 4 Zn 30 0.041536 7.431441 10.654502 30.00 65.3800
SCF PARAMETERS Density guess: RESTART
--------------------------------------------------------
max_scf: 50
max_scf_history: 0
max_diis: 4
--------------------------------------------------------
eps_scf: 1.00E-05
eps_scf_history: 0.00E+00
eps_diis: 1.00E-01
eps_eigval: 1.00E-05
--------------------------------------------------------
level_shift [a.u.]: 0.00
--------------------------------------------------------
No outer SCF
PW_GRID| Information for grid number 1
PW_GRID| Grid distributed over 20 processors
PW_GRID| Real space group dimensions 20 1
PW_GRID| the grid is blocked: NO
PW_GRID| Cutoff [a.u.] 250.0
PW_GRID| spherical cutoff: NO
PW_GRID| Bounds 1 -60 59 Points: 120
PW_GRID| Bounds 2 -60 59 Points: 120
PW_GRID| Bounds 3 -90 89 Points: 180
PW_GRID| Volume element (a.u.^3) 0.2129E-02 Volume (a.u.^3) 5517.7706
PW_GRID| Grid span FULLSPACE
PW_GRID| Distribution Average Max Min
PW_GRID| G-Vectors 129600.0 129600 129600
PW_GRID| G-Rays 1080.0 1080 1080
PW_GRID| Real Space Points 129600.0 129600 129600
PW_GRID| Information for grid number 2
PW_GRID| Grid distributed over 20 processors
PW_GRID| Real space group dimensions 20 1
PW_GRID| the grid is blocked: NO
PW_GRID| Cutoff [a.u.] 83.3
PW_GRID| spherical cutoff: NO
PW_GRID| Bounds 1 -36 35 Points: 72
PW_GRID| Bounds 2 -36 35 Points: 72
PW_GRID| Bounds 3 -50 49 Points: 100
PW_GRID| Volume element (a.u.^3) 0.1064E-01 Volume (a.u.^3) 5517.7706
PW_GRID| Grid span FULLSPACE
PW_GRID| Distribution Average Max Min
PW_GRID| G-Vectors 25920.0 26208 25488
PW_GRID| G-Rays 360.0 364 354
PW_GRID| Real Space Points 25920.0 28800 21600
PW_GRID| Information for grid number 3
PW_GRID| Grid distributed over 20 processors
PW_GRID| Real space group dimensions 20 1
PW_GRID| the grid is blocked: NO
PW_GRID| Cutoff [a.u.] 27.8
PW_GRID| spherical cutoff: NO
PW_GRID| Bounds 1 -20 19 Points: 40
PW_GRID| Bounds 2 -20 19 Points: 40
PW_GRID| Bounds 3 -30 29 Points: 60
PW_GRID| Volume element (a.u.^3) 0.5748E-01 Volume (a.u.^3) 5517.7706
PW_GRID| Grid span FULLSPACE
PW_GRID| Distribution Average Max Min
PW_GRID| G-Vectors 4800.0 4840 4760
PW_GRID| G-Rays 120.0 121 119
PW_GRID| Real Space Points 4800.0 4800 4800
PW_GRID| Information for grid number 4
PW_GRID| Grid distributed over 20 processors
PW_GRID| Real space group dimensions 20 1
PW_GRID| the grid is blocked: NO
PW_GRID| Cutoff [a.u.] 9.3
PW_GRID| spherical cutoff: NO
PW_GRID| Bounds 1 -12 11 Points: 24
PW_GRID| Bounds 2 -12 11 Points: 24
PW_GRID| Bounds 3 -18 17 Points: 36
PW_GRID| Volume element (a.u.^3) 0.2661 Volume (a.u.^3) 5517.7706
PW_GRID| Grid span FULLSPACE
PW_GRID| Distribution Average Max Min
PW_GRID| G-Vectors 1036.8 1152 936
PW_GRID| G-Rays 43.2 48 39
PW_GRID| Real Space Points 1036.8 1728 864
POISSON| Solver PERIODIC
POISSON| Periodicity XYZ
RS_GRID| Information for grid number 1
RS_GRID| Bounds 1 -60 59 Points: 120
RS_GRID| Bounds 2 -60 59 Points: 120
RS_GRID| Bounds 3 -90 89 Points: 180
RS_GRID| Real space fully replicated
RS_GRID| Group size 1
RS_GRID| Information for grid number 2
RS_GRID| Bounds 1 -36 35 Points: 72
RS_GRID| Bounds 2 -36 35 Points: 72
RS_GRID| Bounds 3 -50 49 Points: 100
RS_GRID| Real space fully replicated
RS_GRID| Group size 1
RS_GRID| Information for grid number 3
RS_GRID| Bounds 1 -20 19 Points: 40
RS_GRID| Bounds 2 -20 19 Points: 40
RS_GRID| Bounds 3 -30 29 Points: 60
RS_GRID| Real space fully replicated
RS_GRID| Group size 1
RS_GRID| Information for grid number 4
RS_GRID| Bounds 1 -12 11 Points: 24
RS_GRID| Bounds 2 -12 11 Points: 24
RS_GRID| Bounds 3 -18 17 Points: 36
RS_GRID| Real space fully replicated
RS_GRID| Group size 1
DISTRIBUTION OF THE PARTICLES (ROWS)
Process row Number of particles Number of matrix rows
0 31 -1
1 38 -1
Sum 69 -1
DISTRIBUTION OF THE PARTICLES (COLUMNS)
Process col Number of particles Number of matrix columns
0 5 -1
1 5 -1
2 7 -1
3 7 -1
4 7 -1
5 8 -1
6 7 -1
7 7 -1
8 8 -1
9 8 -1
Sum 69 -1
DISTRIBUTION OF THE NEIGHBOR LISTS
Total number of particle pairs: 11189
Total number of matrix elements: 1496630
Average number of particle pairs: 560
Maximum number of particle pairs: 680
Average number of matrix element: 74832
Maximum number of matrix elements: 98909
DISTRIBUTION OF THE OVERLAP MATRIX
Number of non-zero blocks: 2415
Percentage non-zero blocks: 100.00
Average number of blocks per CPU: 121
Maximum number of blocks per CPU: 163
Average number of matrix elements per CPU: 13426
Maximum number of matrix elements per CPU: 14857
Number of electrons: 348
Number of occupied orbitals: 174
Number of molecular orbitals: 174
Number of orbital functions: 726
Number of independent orbital functions: 726
Extrapolation method: initial_guess
SCF WAVEFUNCTION OPTIMIZATION
----------------------------------- OT ---------------------------------------
Minimizer : CG : conjugate gradient
Preconditioner : FULL_KINETIC : inversion of T + eS
Precond_solver : DEFAULT
Line search : 2PNT : 2 energies, one gradient
stepsize : 0.15000000 energy_gap : 0.20000000
eps_taylor : 0.10000E-15 max_taylor : 4
----------------------------------- OT ---------------------------------------
Step Update method Time Convergence Total energy Change
------------------------------------------------------------------------------
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191017330 108.4808982670
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365999701 -504.4557204739
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812292
Total charge density (r-space): 0.0000187708
Total Rho_soft + Rho0_soft (g-space): 0.0000079490
1 OT CG 0.15E+00 2.1 0.00086934 -6924.6842285510 -6.92E+03
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5251606151 108.4748393849
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9338609473 -504.4590403866
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999811757
Total charge density (r-space): 0.0000188243
Total Rho_soft + Rho0_soft (g-space): 0.0000080140
2 OT LS 0.15E-02 1.7 -6922.5986745791
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191018708 108.4808981292
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365989168 -504.4557195591
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812285
Total charge density (r-space): 0.0000187715
Total Rho_soft + Rho0_soft (g-space): 0.0000079497
3 OT CG 0.15E-02 3.1 0.00183175 -6924.6841616942 6.69E-05
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191030451 108.4808969549
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365984976 -504.4557203125
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812301
Total charge density (r-space): 0.0000187699
Total Rho_soft + Rho0_soft (g-space): 0.0000079480
4 OT LS 0.44E-03 1.7 -6924.6837184848
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191015683 108.4808984317
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365992442 -504.4557195835
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812290
Total charge density (r-space): 0.0000187710
Total Rho_soft + Rho0_soft (g-space): 0.0000079492
5 OT CG 0.44E-03 3.1 0.00023282 -6924.6842553514 -9.37E-05
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191015330 108.4808984670
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365991487 -504.4557194526
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812291
Total charge density (r-space): 0.0000187709
Total Rho_soft + Rho0_soft (g-space): 0.0000079491
6 OT LS 0.62E-03 1.7 -6924.6842573008
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191015205 108.4808984795
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365991096 -504.4557194010
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812291
Total charge density (r-space): 0.0000187709
Total Rho_soft + Rho0_soft (g-space): 0.0000079491
7 OT CG 0.62E-03 3.1 0.00007379 -6924.6842574777 -2.13E-06
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191014818 108.4808985182
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365989661 -504.4557192187
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812291
Total charge density (r-space): 0.0000187709
Total Rho_soft + Rho0_soft (g-space): 0.0000079491
8 OT LS 0.97E-03 1.7 -6924.6842577677
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191014607 108.4808985393
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365988860 -504.4557191176
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812291
Total charge density (r-space): 0.0000187709
Total Rho_soft + Rho0_soft (g-space): 0.0000079491
9 OT CG 0.97E-03 3.1 0.00005381 -6924.6842578104 -3.33E-07
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191013844 108.4808986156
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365985815 -504.4557187367
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812292
Total charge density (r-space): 0.0000187708
Total Rho_soft + Rho0_soft (g-space): 0.0000079490
10 OT LS 0.17E-02 1.7 -6924.6842580652
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191013259 108.4808986741
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365983411 -504.4557184378
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812293
Total charge density (r-space): 0.0000187707
Total Rho_soft + Rho0_soft (g-space): 0.0000079489
11 OT CG 0.17E-02 3.1 0.00004599 -6924.6842581266 -3.16E-07
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191011751 108.4808988249
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365977552 -504.4557177010
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812293
Total charge density (r-space): 0.0000187707
Total Rho_soft + Rho0_soft (g-space): 0.0000079489
12 OT LS 0.93E-03 1.7 -6924.6842581602
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191012436 108.4808987564
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365980255 -504.4557180398
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812293
Total charge density (r-space): 0.0000187707
Total Rho_soft + Rho0_soft (g-space): 0.0000079489
13 OT CG 0.93E-03 3.6 0.00002829 -6924.6842582511 -1.25E-07
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191011894 108.4808988106
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365978237 -504.4557177837
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812293
Total charge density (r-space): 0.0000187707
Total Rho_soft + Rho0_soft (g-space): 0.0000079488
14 OT LS 0.12E-02 1.8 -6924.6842583097
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191011721 108.4808988279
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365977591 -504.4557177019
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812293
Total charge density (r-space): 0.0000187707
Total Rho_soft + Rho0_soft (g-space): 0.0000079488
15 OT CG 0.12E-02 3.3 0.00002630 -6924.6842583134 -6.22E-08
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191010895 108.4808989105
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365974644 -504.4557173244
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812294
Total charge density (r-space): 0.0000187706
Total Rho_soft + Rho0_soft (g-space): 0.0000079488
16 OT LS 0.13E-02 1.7 -6924.6842583712
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191010827 108.4808989173
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365974402 -504.4557172935
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812294
Total charge density (r-space): 0.0000187706
Total Rho_soft + Rho0_soft (g-space): 0.0000079488
17 OT CG 0.13E-02 3.1 0.00001976 -6924.6842583715 -5.81E-08
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191010185 108.4808989815
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365972180 -504.4557170070
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812295
Total charge density (r-space): 0.0000187705
Total Rho_soft + Rho0_soft (g-space): 0.0000079487
18 OT LS 0.10E-02 1.7 -6924.6842583946
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191010331 108.4808989669
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365972689 -504.4557170726
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812295
Total charge density (r-space): 0.0000187705
Total Rho_soft + Rho0_soft (g-space): 0.0000079487
19 OT CG 0.10E-02 3.1 0.00001332 -6924.6842583968 -2.53E-08
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191010033 108.4808989967
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365971757 -504.4557169496
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812295
Total charge density (r-space): 0.0000187705
Total Rho_soft + Rho0_soft (g-space): 0.0000079487
20 OT LS 0.22E-02 1.7 -6924.6842584146
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191009683 108.4808990317
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365970649 -504.4557168036
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812295
Total charge density (r-space): 0.0000187705
Total Rho_soft + Rho0_soft (g-space): 0.0000079486
21 OT CG 0.22E-02 3.0 0.00001555 -6924.6842584220 -2.51E-08
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191008691 108.4808991309
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365967308 -504.4557163703
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812296
Total charge density (r-space): 0.0000187704
Total Rho_soft + Rho0_soft (g-space): 0.0000079485
22 OT LS 0.91E-03 1.7 -6924.6842584059
Trace(PS): 348.0000000000
Electronic density on regular grids: -239.5191009278 108.4808990722
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365969297 -504.4557166279
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812296
Total charge density (r-space): 0.0000187704
Total Rho_soft + Rho0_soft (g-space): 0.0000079486
23 OT CG 0.91E-03 3.1 0.00000823 -6924.6842584358 -1.39E-08
*** SCF run converged in 23 steps ***
Electronic density on regular grids: -239.5191009278 108.4808990722
Core density on regular grids: 348.0000000000 -0.0000000000
Hard and soft densities (Lebedev): -612.9365969297 -504.4557166279
Total Rho_soft + Rho1_hard - Rho1_soft -347.9999812296
Total charge density (r-space): 0.0000187704
Total Rho_soft + Rho0_soft (g-space): 0.0000079486
Overlap energy of the core charge distribution: 0.00004281027620
Self energy of the core charge distribution: -3554.77958145173488
Core Hamiltonian energy: -3448.27477307766549
Hartree energy: 853.53857812863066
Exchange-correlation energy: -128.68082048183405
GAPW| Exc from hard and soft atomic rho1: -305.74230596149761
GAPW| local Eh = 1 center integrals: -340.74539840201498
Total energy: -6924.68425843584009
!-----------------------------------------------------------------------------!
Mulliken Population Analysis
# Atom Element Kind Atomic population Net charge
1 H 1 0.853155 0.146845
2 H 1 0.853845 0.146155
3 H 1 0.852905 0.147095
4 H 1 0.853822 0.146178
5 H 1 0.852910 0.147090
6 H 1 0.863635 0.136365
7 H 1 0.864725 0.135275
8 H 1 0.864294 0.135706
9 H 1 0.864749 0.135251
10 H 1 0.864293 0.135707
11 H 1 0.843810 0.156190
12 H 1 0.843460 0.156540
13 H 1 0.843345 0.156655
14 H 1 0.843458 0.156542
15 H 1 0.843356 0.156644
16 H 1 0.868014 0.131986
17 H 1 0.866471 0.133529
18 H 1 0.867682 0.132318
19 H 1 0.866476 0.133524
20 H 1 0.867693 0.132307
21 H 1 0.879877 0.120123
22 H 1 0.882895 0.117105
23 H 1 0.883343 0.116657
24 H 1 0.882903 0.117097
25 H 1 0.883316 0.116684
26 H 1 0.879887 0.120113
27 H 1 0.868000 0.132000
28 H 1 0.843811 0.156189
29 H 1 0.863632 0.136368
30 H 1 0.853150 0.146850
31 C 2 5.745526 0.254474
32 C 2 5.746476 0.253524
33 C 2 5.748438 0.251562
34 C 2 5.746503 0.253497
35 C 2 5.748420 0.251580
36 C 2 6.095311 -0.095311
37 C 2 6.097751 -0.097751
38 C 2 6.099194 -0.099194
39 C 2 6.097802 -0.097802
40 C 2 6.099144 -0.099144
41 C 2 6.105450 -0.105450
42 C 2 6.102919 -0.102919
43 C 2 6.104750 -0.104750
44 C 2 6.102907 -0.102907
45 C 2 6.104810 -0.104810
46 C 2 6.439911 -0.439911
47 C 2 6.439372 -0.439372
48 C 2 6.441495 -0.441495
49 C 2 6.439365 -0.439365
50 C 2 6.441473 -0.441473
51 C 2 6.439912 -0.439912
52 C 2 6.105464 -0.105464
53 C 2 6.095287 -0.095287
54 C 2 5.745507 0.254493
55 N 3 7.254336 -0.254336
56 N 3 7.254891 -0.254891
57 N 3 7.257115 -0.257115
58 N 3 7.254946 -0.254946
59 N 3 7.257011 -0.257011
60 N 3 7.245694 -0.245694
61 N 3 7.244480 -0.244480
62 N 3 7.247607 -0.247607
63 N 3 7.244468 -0.244468
64 N 3 7.247539 -0.247539
65 N 3 7.245499 -0.245499
66 N 3 7.254241 -0.254241
67 Zn 4 29.599632 0.400368
68 Zn 4 29.598212 0.401788
69 Zn 4 29.598231 0.401769
# Total charge 348.000000 -0.000000
!-----------------------------------------------------------------------------!
!-----------------------------------------------------------------------------!
Hirshfeld Charges
#Atom Element Kind Ref Charge Population Net charge
1 H 1 1.000 0.815 0.185
2 H 1 1.000 0.814 0.186
3 H 1 1.000 0.816 0.184
4 H 1 1.000 0.814 0.186
5 H 1 1.000 0.816 0.184
6 H 1 1.000 0.805 0.195
7 H 1 1.000 0.807 0.193
8 H 1 1.000 0.806 0.194
9 H 1 1.000 0.807 0.193
10 H 1 1.000 0.805 0.195
11 H 1 1.000 0.827 0.173
12 H 1 1.000 0.827 0.173
13 H 1 1.000 0.827 0.173
14 H 1 1.000 0.827 0.173
15 H 1 1.000 0.827 0.173
16 H 1 1.000 0.804 0.196
17 H 1 1.000 0.804 0.196
18 H 1 1.000 0.804 0.196
19 H 1 1.000 0.804 0.196
20 H 1 1.000 0.804 0.196
21 H 1 1.000 0.806 0.194
22 H 1 1.000 0.806 0.194
23 H 1 1.000 0.806 0.194
24 H 1 1.000 0.806 0.194
25 H 1 1.000 0.806 0.194
26 H 1 1.000 0.806 0.194
27 H 1 1.000 0.804 0.196
28 H 1 1.000 0.827 0.173
29 H 1 1.000 0.805 0.195
30 H 1 1.000 0.815 0.185
31 C 2 6.000 5.788 0.212
32 C 2 6.000 5.789 0.211
33 C 2 6.000 5.789 0.211
34 C 2 6.000 5.789 0.211
35 C 2 6.000 5.789 0.211
36 C 2 6.000 6.102 -0.102
37 C 2 6.000 6.102 -0.102
38 C 2 6.000 6.102 -0.102
39 C 2 6.000 6.102 -0.102
40 C 2 6.000 6.102 -0.102
41 C 2 6.000 6.107 -0.107
42 C 2 6.000 6.108 -0.108
43 C 2 6.000 6.108 -0.108
44 C 2 6.000 6.108 -0.108
45 C 2 6.000 6.108 -0.108
46 C 2 6.000 6.459 -0.459
47 C 2 6.000 6.459 -0.459
48 C 2 6.000 6.459 -0.459
49 C 2 6.000 6.459 -0.459
50 C 2 6.000 6.459 -0.459
51 C 2 6.000 6.459 -0.459
52 C 2 6.000 6.107 -0.107
53 C 2 6.000 6.102 -0.102
54 C 2 6.000 5.788 0.212
55 N 3 7.000 6.861 0.139
56 N 3 7.000 6.861 0.139
57 N 3 7.000 6.862 0.138
58 N 3 7.000 6.861 0.139
59 N 3 7.000 6.862 0.138
60 N 3 7.000 6.858 0.142
61 N 3 7.000 6.859 0.141
62 N 3 7.000 6.861 0.139
63 N 3 7.000 6.859 0.141
64 N 3 7.000 6.861 0.139
65 N 3 7.000 6.858 0.142
66 N 3 7.000 6.861 0.139
67 Zn 4 30.000 31.532 -1.532
68 Zn 4 30.000 31.525 -1.525
69 Zn 4 30.000 31.525 -1.525
Total Charge 0.000
!-----------------------------------------------------------------------------!
Eigenvalues of the occupied subspace spin 1
---------------------------------------------
-345.47682748 -345.47682178 -345.47676178 -41.43050877
-41.43050572 -41.43049154 -36.51466861 -36.51466671
-36.51462248 -36.51385807 -36.51384235 -36.51382287
-36.51355379 -36.51354517 -36.51354288 -13.81855701
-13.81855507 -13.81852483 -13.81851439 -13.81845407
-13.81844805 -13.81823246 -13.81821912 -13.81821636
-13.81820839 -13.81815686 -13.81815589 -9.76662726
-9.76661750 -9.76659289 -9.76658709 -9.76648589
-9.76647824 -9.72685197 -9.72684808 -9.72670511
-9.72669690 -9.72667824 -9.72667303 -9.72613397
-9.72613270 -9.72590596 -9.72590574 -9.72581536
-9.72581170 -9.71280032 -9.71279283 -9.71274361
-9.71273730 -9.71271186 -9.71271114 -4.41539987
-4.41539797 -4.41536789 -2.85036887 -2.85036742
-2.85027944 -2.84880376 -2.84879900 -2.84876109
-2.84820348 -2.84816816 -2.84816611 -0.72517895
-0.72341973 -0.72329353 -0.72233238 -0.72220640
-0.72165051 -0.58601722 -0.58588499 -0.58087215
-0.57943830 -0.57828454 -0.57819286 -0.50801225
-0.50679141 -0.50676925 -0.50665351 -0.50523226
-0.50520430 -0.43224265 -0.42968185 -0.42958576
-0.42313923 -0.42312453 -0.42117685 -0.34779766
-0.34555679 -0.34548262 -0.33919312 -0.33906009
-0.33128884 -0.32468032 -0.30585828 -0.30584376
-0.30454424 -0.30445814 -0.30209565 -0.28203431
-0.27130812 -0.27112465 -0.26860651 -0.26856615
-0.26041113 -0.22441428 -0.22424898 -0.22065450
-0.21766277 -0.21759778 -0.21203919 -0.21201473
-0.21117738 -0.20739588 -0.20575284 -0.20567712
-0.20203592 -0.20184337 -0.20175687 -0.19814380
-0.19785985 -0.19763248 -0.19745596 -0.19302886
-0.19174716 -0.19173037 -0.19136310 -0.19116873
-0.18901916 -0.18778576 -0.18777089 -0.18651071
-0.16833081 -0.16507228 -0.16494953 -0.16165888
-0.16156427 -0.16131387 -0.16129950 -0.15635289
-0.15422376 -0.15421443 -0.15144546 -0.15128126
-0.14853624 -0.14794206 -0.14532138 -0.14504654
-0.14473907 -0.14468560 -0.14279781 -0.14156947
-0.14151346 -0.10108107 -0.09745127 -0.09720809
-0.08774796 -0.08763878 -0.07535714 -0.06283111
-0.05715899 -0.05705192 -0.05609758 -0.05599804
-0.05471580 -0.04180217 -0.04172141 -0.03857862
-0.00740241 -0.00724671 -0.00400202 0.00209418
0.00326735 0.00335001
Fermi Energy [eV] : 0.091158
Lowest Eigenvalues of the unoccupied subspace spin 1
-----------------------------------------------------
Reached convergence in 145 iterations
0.18018462 0.18108553 0.18498253 0.18512932
0.18880690 0.19055018 0.19066608 0.19187474
0.19562087 0.19604811 0.20194424 0.20503915
0.20549343 0.23788247 0.23819327 0.24082936
0.24592790 0.26133487 0.26201399 0.26925967
0.27137678 0.27161566 0.27455229 0.27681499
0.27770267 0.27825832 0.27865586 0.28733183
0.28813163 0.28913187 0.28927794 0.29776203
0.29811446 0.30141447 0.31388246 0.31554330
0.32267100 0.32281592 0.32804106 0.32994627
0.33088116 0.33977008 0.34056673 0.34057526
0.35351195 0.35678290 0.35696818 0.35838482
0.36589884 0.36596777 0.36819246 0.36826742
0.37441735 0.37535122 0.37999290 0.39114193
0.39192347 0.40023714 0.40048075 0.40485490
0.40915309 0.41071086 0.41419208 0.41540601
0.41844338 0.41891313 0.42250466 0.42512382
0.42892713 0.42945999 0.43312292 0.43938750
0.44712281 0.45152811 0.45191607 0.46004552
0.46126026 0.46375930 0.47014090 0.47952602
0.48001604 0.48512254 0.48916900 0.49135793
0.49277666 0.49351047 0.50252612 0.50307994
0.51999316 0.52055173 0.52116288 0.52991493
0.53049826 0.53295929 0.53782093 0.54034313
0.54631512 0.54829879 0.55107926 0.55475100
0.56199044 0.56212916 0.57096100 0.57214706
0.58475535 0.58502336 0.59027935 0.59260738
0.60078864 0.60165316 0.60549028 0.60609832
0.61050129 0.62160112 0.62195230 0.62382898
0.62671524 0.62687010 0.62975936 0.64082365
0.64839000 0.64894597 0.65301174 0.65313658
0.65411455 0.65432939 0.65599264 0.66117123
0.66165788 0.66342041 0.67609047 0.67758988
0.68946083 0.69189465 0.69279512 0.69820042
0.69896612 0.70006467 0.70161809 0.70218445
0.70450773 0.71074452 0.72936612 0.72961647
0.73382245 0.73985436 0.74482100 0.74537472
0.74681162 0.74742266
HOMO - LUMO gap [eV] : 4.811914
ENERGY| Total FORCE_EVAL ( QS ) energy (a.u.): -6924.684258435840093
*******************************************************************************
*******************************************************************************
** **
** ######## ####### ####### ######## ######## **
** ## ## # ## # ## ## **
** ## ## ## ## ## ## ## **
** ## ## ## ## ## ###### ## **
** ## ## ## ## ## ## ## **
** ## ## # ## # ## ## T.Chassaing and J.Hutter **
** ## ####### ####### ## ## 2005 **
** **
** Calculation Started.. **
*******************************************************************************
*******************************************************************************
Generating initial guess
nvec Convergence
-----------------------------------------------------------------------------
4.8119144 6.4718E-13
4.8141637 5.3346E-14
4.8364293 6.1408E-12
6 6.1408E-12
Doing TDDFPT calculation
nvec Convergence
-----------------------------------------------------------------------------
KPP1 total charge density (r-space): -0.0000226810
KPP1 total charge density (g-space): -0.0000226810
KPP1 total charge density (r-space): 0.0008501219
KPP1 total charge density (g-space): 0.0008501219
KPP1 total charge density (r-space): -0.0002691746
KPP1 total charge density (g-space): 0.0001715982
KPP1 total charge density (r-space): 0.0006427453
KPP1 total charge density (g-space): -1.5556926526
KPP1 total charge density (r-space): 0.0091207066
KPP1 total charge density (g-space): 4938.3527780058
KPP1 total charge density (r-space): 0.0002126590
KPP1 total charge density (g-space): -14420257.3201026358
********** 1.8190E+10
********** 3.0963E+06
4.9714949 6.6701E-02
6 1.8190E+10
KPP1 total charge density (r-space): -0.0039578545
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0011057537
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0011574219
KPP1 total charge density (g-space): ********************
********** 4.3826E+20
********** 6.2389E+15
********** 1.2496E+13
9 4.3826E+20
KPP1 total charge density (r-space): -0.0079954133
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0017211016
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0032743433
KPP1 total charge density (g-space): ********************
********** 4.5743E+30
********** 8.3988E+24
********** 6.9350E+16
12 4.5743E+30
KPP1 total charge density (r-space): 0.0154979047
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.1374810390
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0753791031
KPP1 total charge density (g-space): ********************
********** 4.7750E+40
********** 1.1765E+35
********** 2.3384E+29
15 4.7750E+40
KPP1 total charge density (r-space): 0.1025428204
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0206866196
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0115826911
KPP1 total charge density (g-space): ********************
********** 4.9859E+50
********** 1.2142E+45
********** 6.3338E+38
18 4.9859E+50
KPP1 total charge density (r-space): -0.0191436417
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.2480869646
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0924982434
KPP1 total charge density (g-space): ********************
********** 5.2073E+60
********** 1.2542E+55
********** 1.4644E+48
21 5.2073E+60
KPP1 total charge density (r-space): 0.0225802861
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.1684894825
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0961321930
KPP1 total charge density (g-space): ********************
********** 5.4399E+70
********** 1.2951E+65
********** 1.3690E+58
24 5.4399E+70
KPP1 total charge density (r-space): -0.3134734576
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0151048356
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0000342542
KPP1 total charge density (g-space): ********************
********** 5.6842E+80
********** 1.3370E+75
********** 1.4198E+68
27 5.6842E+80
KPP1 total charge density (r-space): -0.0178141007
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0577568836
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0018205530
KPP1 total charge density (g-space): ********************
********** 5.9407E+90
********** 1.3799E+85
********** 1.4747E+78
30 5.9407E+90
KPP1 total charge density (r-space): -0.0671525794
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0345899753
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.1052013014
KPP1 total charge density (g-space): ********************
********** 6.2101+100
********** 1.4240E+95
********** 1.5319E+88
33 6.2101+100
KPP1 total charge density (r-space): -0.2161664723
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0340562803
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0840694061
KPP1 total charge density (g-space): ********************
********** 6.4930+110
********** 1.4691+105
********** 1.5912E+98
36 6.4930+110
KPP1 total charge density (r-space): 0.0313945922
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0079361983
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0356127221
KPP1 total charge density (g-space): ********************
********** 6.7901+120
********** 1.5154+115
********** 1.6529+108
39 6.7901+120
KPP1 total charge density (r-space): -0.0487083125
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0560686509
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0012228672
KPP1 total charge density (g-space): ********************
********** 7.1021+130
********** 1.5629+125
********** 1.7170+118
42 7.1021+130
KPP1 total charge density (r-space): 0.0347827747
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0544344408
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0224921949
KPP1 total charge density (g-space): ********************
********** 7.4298+140
********** 1.6115+135
********** 1.7837+128
45 7.4298+140
KPP1 total charge density (r-space): 0.0694225815
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0783440495
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0363626420
KPP1 total charge density (g-space): ********************
********** 7.7738+150
********** 1.6614+145
********** 1.8529+138
48 7.7738+150
KPP1 total charge density (r-space): -0.0146633908
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0213225126
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0170893955
KPP1 total charge density (g-space): ********************
********** 8.1351+160
********** 1.7126+155
********** 1.9249+148
51 8.1351+160
KPP1 total charge density (r-space): -0.0318772929
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0402707544
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0190333464
KPP1 total charge density (g-space): ********************
********** 8.5144+170
********** 1.7651+165
********** 1.9997+158
54 8.5144+170
KPP1 total charge density (r-space): -0.0263884969
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0019325894
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0424907885
KPP1 total charge density (g-space): ********************
********** 8.9127+180
********** 1.8190+175
********** 2.0774+168
57 8.9127+180
KPP1 total charge density (r-space): 0.0135632015
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0543710305
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0702817738
KPP1 total charge density (g-space): ********************
********** 9.3308+190
********** 1.8742+185
********** 2.1583+178
60 9.3308+190
KPP1 total charge density (r-space): 0.0458125538
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0210002367
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0008410440
KPP1 total charge density (g-space): ********************
********** 9.7699+200
********** 1.9309+195
********** 2.2422+188
63 9.7699+200
KPP1 total charge density (r-space): 0.0965456951
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0259461987
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0150062926
KPP1 total charge density (g-space): ********************
********** 1.0231+211
********** 1.9891+205
********** 2.3296+198
66 1.0231+211
KPP1 total charge density (r-space): 0.0414021521
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0932316631
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0981888996
KPP1 total charge density (g-space): ********************
********** 1.0715+221
********** 2.0488+215
********** 2.4202+208
69 1.0715+221
KPP1 total charge density (r-space): 0.0051978130
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0682355591
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0038309898
KPP1 total charge density (g-space): ********************
********** 1.1222+231
********** 2.1100+225
********** 2.5146+218
72 1.1222+231
KPP1 total charge density (r-space): 0.0025601905
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.2236519709
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0503004103
KPP1 total charge density (g-space): ********************
********** 1.1756+241
********** 2.1729+235
********** 2.6126+228
75 1.1756+241
KPP1 total charge density (r-space): 0.0365768115
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.1456798139
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0469106450
KPP1 total charge density (g-space): ********************
********** 1.2315+251
********** 2.2374+245
********** 2.7145+238
78 1.2315+251
KPP1 total charge density (r-space): 0.0744989175
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0680390997
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0152012006
KPP1 total charge density (g-space): ********************
********** 1.2902+261
********** 2.3037+255
********** 2.8205+248
81 1.2902+261
KPP1 total charge density (r-space): -0.0374589345
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0018217495
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0439657508
KPP1 total charge density (g-space): ********************
********** 1.3519+271
********** 2.3718+265
********** 2.9305+258
84 1.3519+271
KPP1 total charge density (r-space): 0.0066407538
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.1565553897
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0377872003
KPP1 total charge density (g-space): ********************
********** 1.4166+281
********** 2.4417+275
********** 3.0449+268
87 1.4166+281
KPP1 total charge density (r-space): -0.0306375354
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0186167463
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0022251235
KPP1 total charge density (g-space): ********************
********** 1.4844+291
********** 2.5135+285
********** 3.1639+278
90 1.4844+291
KPP1 total charge density (r-space): -0.0363571198
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): -0.0811410117
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0351298159
KPP1 total charge density (g-space): ********************
********** 1.5556+301
********** 2.5872+295
********** 3.2876+288
93 1.5556+301
KPP1 total charge density (r-space): 0.0648396419
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0141301028
KPP1 total charge density (g-space): ********************
KPP1 total charge density (r-space): 0.0445581317
KPP1 total charge density (g-space): NaN
** On entry to DLASCLS, parameter number 4 had an illegal value
** On entry to DLASCLS, parameter number 4 had an illegal value
** On entry to DLASCLS, parameter number 4 had an illegal value
** On entry to DLASCLS, parameter number 4 had an illegal value
** On entry to DLASCLS, parameter number 4 had an illegal value
** On entry to DLASCLS, parameter number 4 had an illegal value
** On entry to DLASCLS, parameter number 4 had an illegal value
** On entry to DLASCLS, parameter number 4 had an illegal value
{ 1, 1}: On entry to DSTEQR parameter number -31 had an illegal value
{ 0, 0}: On entry to DSTEQR parameter number -31 had an illegal value
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