Get custom product attribute from quote item.
Will reload all product data from the database. While this will work, bear in mind that every time you call load() Magento will execute a database query.
// load product
$_product = $_item->getProduct()->load(); // or Mage::getModel('catalog/product')->load($_item->getProductId());
// then get attribute from product
$_product->getCustomAttributeCode(); <global>
<sales>
<quote>
<item>
<product_attributes>
<custom_attribute_code />
</product_attributes>
</item>
</quote>
</sales>
</global>Having done that, you can access your custom attribute without additional database queries.
$_item->getProduct()->getCustomAttributeCode();