This assumes you are now connected to the server via SSH.
sudo -s
Enter root mode for admin accessgroupadd devgroup
Create new group to be later granted access to /var/www/html
useradd -G root,devgroup masterdev
Create new root user. Also add to the devgrouppasswd masterdev
Change password for the new root user- At this point, you'll need to input your new root user's new password