diagram.tex

\documentclass[10pt]{article}

% I only need the arrows for this one.
\usepackage{tikz}
\usetikzlibrary{arrows}

% Nice captions.
\usepackage[hang,small,bf]{caption}
\setlength{\captionmargin}{25pt}

% New commands to keep things tidy.
\newcommand{\ket}[1]{$\left|#1\right\rangle$}
\newcommand{\Om}[1]{\small $\omega_{#1}$}
\newcommand{\De}[1]{$\Delta_{#1}$}
\newcommand{\Ga}[1]{$\Gamma_{#1}$}

\begin{document}

% Place the TikZ picture in a figure environment.
\begin{figure}
\centerline{
  % Resize it to 5cm wide.
  \resizebox{7cm}{!}{
    \begin{tikzpicture}[
      scale=0.5,
      level/.style={thick},
      virtual/.style={thick,densely dashed},
      direct/.style={thick,<-,shorten >=2pt,shorten <=2pt,>=stealth},
      trans/.style={thick,<->,shorten >=2pt,shorten <=2pt,>=stealth},
      classical/.style={thin,double,<->,shorten >=4pt,shorten <=4pt,>=stealth}
    ]
    % Draw the energy levels.
    \draw[level] (2cm,-2em) -- (0cm,-2em) node[left] {\ket{i}};
    \draw[level] (2cm,11em) -- (4cm,11em) node[midway,above] {\ket{e}};
    \draw[level] (4cm,-11em) -- (6cm,-11em) node[right] {\ket{f}};
    % Draw the transitions.
    \draw[direct] (1cm,-2em) -- (3cm,10em) node[midway,left] {$\Gamma_e$};
    \draw[trans] (3.5cm,10em) -- (5cm,-10em) node[midway,right] {$W$};
    \draw[direct] (4.5cm,-10em) -- (1.5cm,-3em) node[midway,below] {$\Gamma_i$};
    \end{tikzpicture}
  }
}
\caption{A level diagram with some transitions drawn in TikZ, resized,
                and placed in a figure environment.}
\end{figure}

\end{document}