You can run the command, specifying env vars as needed:
$ CHOP_DEBUG=true CHOP_LISTEN_PORT=123 CHOP_REDIS_HOST=asdfasdfasdf CHOP_MULTIPLIER=123.4 crystal run env2.cr
Which, given the configuration specified earlier, gives the following output:
prefix: something
redis_host: asdfasdfasdf
redis_port: 6379
debug: true
Settings ---------------------------------------------
* prefix: "something"
* redis_host: "asdfasdfasdf"
* redis_port: 6379
* listen_port: 123
* default_url: nil
* multiplier: 123.4
* debug: true
-------------------------------------------------------