The main trick here is the new Multiarch on Ubuntu Saucy and the need to enable it separately for Crouton.
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Install Crouton
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Install saucy
sudo sh -e ~/Downloads/crouton -t xfce -r saucy -
Start the chroot
sudo startxfce4 -
Download and extract Android SDK starter
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Install Java 7
sudo apt-get install openjdk-7-jre -
Download platform tools
cd ~/android-sdk-linux/tools ./android -
Enable i386
sudo dpkg --add-architecture i386 sudo apt-get update -
Install ADB i386 dependencies
sudo apt-get install libc6:i386 libstdc++6:i386 -
Run ADB
cd ~/android-sdk-linux/platform-tools ./adb